The 'quick carb' (high PSI, shake keg/CO2 stone) vs. 'low and slow' carbonation ("set it and forget it") debate seems to be hinged on the issue of CO2 hydration/hydrolysis (not sure which, will correct when someone tells me). Beer that is carbed slowly will have hydrolyzed CO2, while beer that is 'quick' carbed will have unhydrolyzed CO2. The parallel to this would be soda that is served from a fountain (carbed h2o mixed with syrup) vs. a soda in can/bottle.
Does it take a full 2 weeks (or some other duration) for CO2 to hydrate/hydrolyze, or could a brewer give the carbonation a head start (by shaking keg at higher PSI), then wait, say one week for the dissolved CO2 to round out?